The American Heritage® Dictionary of the English Language, 4th Edition
pronoun. Used to indicate the one or ones belonging to thee.
adj. Used instead of thy before an initial vowel or h: "The presidential candidates are practicing the first rule of warfare: know thine enemy” ( Eleanor Clift).
determiner. Singular second person prevocalic possessive determiner (preconsonantal form: thy).
pronoun. Singular second person possessive pronoun.
the GNU version of the Collaborative International Dictionary of English
preposition. A form of the possessive case of the pronoun thou, now superseded in common discourse by your, the possessive of you, but maintaining a place in solemn discourse, in poetry, and in the usual language of the Friends, or Quakers.
The Century Dictionary and Cyclopedia
Of thee; the original genitive of the pronoun thou.
Of thee; belonging to thee. Compare mine, 2.
Belonging or pertaining to thee: in this sense a possessive.
Used attributively, with the force of an adjective: commonly preferred before a vowel to thy, and now used only in that situation.
Word Usage
"Before a noun beginning with a vowel thine and mine are commonly substituted for thy and my, as in thine eyes and mine infirmity."